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Springtown Union 76
4700 1st St, Livermore, CA 94551
Springtown Union 76 is located in downtown Livermore right off the 580 Freeway. Union76  is a full service gasMore station with full service convenience store. It has mechanics on duty during the week. They'll do repairs, tune-ups and oil changes among many services. They can often give you a price quote over the phone. 
CTV Enterprises
1771 1st St, Livermore, CA 94550
CTV Enterprises is an independent gas station in downtown Livermore that tends to have better prices than some ofMore the larger conglomerates. It is self-serve and you can pay with a credit card. 
Arco AM PM
785 E Stanley Blvd, Livermore, CA 94550
This large corner gas station has 12 fuel pumps, which only take cash or ATM cards. The station is open 24 hours a dayMore and is frequently busy because it keeps its fuel prices at or near the lowest in the area. Rebuilt in 2008, the station now features a modern-looking store, which is stocked with a good selection of food, drinks and convenience items.
Rotten Robbie 64
4186 East Ave, Livermore, CA 94550
This branch of the famous fuel franchise is conveniently situated right near the Chardonnay Center shopping strip. TheMore gas is competitively priced, and the station has an expansive store, roughly the size of a small supermarket. There are hundreds of items to choose from, including the usual snacks, batteries, prepaid cards and lottery tickets. The staff is friendly and the fresh-brewed coffee is of better quality than you would normally expect from a convenience store.